Thermal Expansion Studies on Cathode and Interconnect Oxides*

EXAFS studies of local thermal expansion

Original information on local thermal expansion can be obtained through a cumulant analysis of EXAFS. The different sensitivity to correlation of the first and third EXAFS cumulants, and their comparison with crystallographic distance, can help in disentangling the contribution of potential anharmonicity to thermal expansion from geometrical effects. These possibilities are illustrated by recen...

The effective parameters on thermal recovery and reduction of iron oxides in EAF slag

Steelmaking slag of Mobarakeh Steel Company (MSC) has a high iron content which makes it unsuitable for conventional slag recovery; as in cement industries. On the other hand, EAF slag in this company is almost free of zinc because of using more than 90 percent DRI in the charge. Therefore, removal or recovery of iron from the slag can be a suitable solution to slag recovery in this company. In...

Novel Materials through Non-Hydrolytic Sol-Gel Processing: Negative Thermal Expansion Oxides and Beyond

Low temperature methods have been applied to the synthesis of many advanced materials. Non-hydrolytic sol-gel (NHSG) processes offer an elegant route to stable and metastable phases at low temperatures. Excellent atomic level homogeneity gives access to polymorphs that are difficult or impossible to obtain by other methods. The NHSG approach is most commonly applied to the preparation of metal ...

Effects on Composite Thermal Expansion

First principles studies on band structures and density of states of graphite surface oxides

Graphite oxide constitutes carbon network with oxygen atoms both on hexagonal arrangement and the edge sites. Structural and electronic properties for graphite-oxygen complexes have been explored using first-principles total-energy calculations within the local density approximation (LDA). Band structures and density of states for the propose carbon 3D models are reported. A finite energy gap and...